ChemInform Abstract: BIMETALLIC CYANO‐BRIDGED CATIONS: PREPARATION AND HYDRIDE REDUCTION OF ((η5‐C5H5)(L2RU(μ‐CN)ML′2(η5‐C5H5))PF6 (L2, L′2 = (PPH3)2, PH2PCH2CH2PPH2; M = RU OR FE). FORMATION OF (RU(η5‐C5H5)(PPH3)H3) AND X‐RAY CRYSTAL STRUCTURE OF 2‐(1,2‐BIS(DIPHENYLPHOSPHINO)ETHANE)‐μ‐CYANO‐1,2‐BIS(η5‐CYCLOPENTADIENYL# )‐1,1‐BIS(TRIPHENYLPHOSPHINE)DIRUTHENIUM(II,II)

Abstract

Die Cyano‐ Komplexe (I) reagieren mit den entsprechenden Ru‐chloriden (II) zu den cyanoverbrückten Dirutheniumkomplexen (lIIa)‐(IIId).