ChemInform Abstract: Binary Ammonium‐Gallium Phosphates.

Chudinova, N. N.; Gruntse, I.; Guzeeva, L. S.

doi:10.1002/chin.198728034

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2010

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“…The title compound was first synthesized by Kanene et al (1985) and its unit cell determined from Weissenberg photographs. Isotypic compounds have been reported: Ga 2 P 6 O 18 (Chudinova et al, 1987); Cr 2 P 6 O 18 (Bagieu-Beucher & Guitel, 1977) and Ru 2 P 6 O 18 (Fukuoka et al, 1995). For a review of the crystal chemistry of cyclohexaphosphates, see: Durif (1995Durif ( , 2005.…”

Section: Related Literaturementioning

confidence: 99%

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Aluminium cyclohexaphosphate

et al. 2010

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Single crystals of the title compound, Al2P6O18, were obtained by solid-state reaction. The monoclinic structure is isotypic with its CrIII, GaIII and RuIII analogues and is built up of six-membered phosphate ring anions, P6O18 6−, isolated from each other and further linked by isolated AlO6 octahedra by sharing corners. Each AlO6 octahedron is linked to four P6O18 6− rings. More accurately, two rings are linked through bidentate diphosphate groups attached in the cis-positions to the AlO6 octahedron. The other two rings are linked to the two remaining corners, also in cis-positions of the AlO6 octahedron.

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Section: Related Literaturementioning

confidence: 99%

“…The crystal structure of Al 2 P 6 0 18 is isotypic with Cr 2 P 6 O 18 (Bagieu-Beucher & Guitel, 1977), Ga 2 P 6 O 18 (Chudinova et al, 1987) and Ru 2 P 6 O 18 (Fukuoka et al, 1995). It is built up of six-membered phosphate ring anions (P 6 O 18 ) 6isolated from each others and further linked by AlO 6 octahedra by sharing corners.…”

Section: Crystal Datamentioning

confidence: 99%