ChemInform Abstract: Carboxamides and Amines Having Two and Three Adamantane Fragments

Kas’yan, L. I.; Karpenko, D. V.; Kas’yan, A. O.; Isaev, A. K.; Prid’ma, S. A.

doi:10.1002/chin.200813062

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Synthesis Of Amino Alcohols From Bi-and Polycyclic Cage-like1

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2010

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“…Studies have been initiated on reactions of cage-like amines with novel epoxy compounds having O-and N- (2,3-epoxypropyl) fragments [67]. The reactions of bicyclo[2.2.1]hept-5-en-endo-2-ylmethanamine (45b) with 1,2-epoxy-3-phenoxypropane and N-(2,3-epoxypropyl)-N-phenylbenzenesulfonamide were carried out in propan-2-ol at room temperature [68], and the products were isolated by chromatography. In the first case, compounds 67 and 68 were formed, while in the second, compound 69 was the only product (Scheme 23).…”

Section: Synthesis Of Amino Alcohols From Bi-and Polycyclic Cage-likementioning

confidence: 99%

Cage-like amino alcohols. synthesis, reactions, and application

Kas’yan

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2010

Russ J Org Chem

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The review analyzes methods for the synthesis of amino alcohols containing cage-like norbornene, norbornane, and adamantane fragments. Such reactions of amino alcohols as selective functionalization of hydroxy and amino groups, as well as heterocyclizations with formation of nitrogen-and oxygen-containing heterocycles, are considered. Biological activity of cage-like amino alcohols and their derivatives and their use as ligands in catalytic asymmetric syntheses are discussed.

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Section: Synthesis Of Amino Alcohols From Bi-and Polycyclic Cage-likementioning

confidence: 99%