ChemInform Abstract: Catalytic 1,4‐Selective Hydrosilylation of Pyridines and Benzannulated Congeners.

Abstract

Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners. -This reaction likely proceeds via an ionic one-step hydride transfer distinguishing it from previously reported methods with radical mechanisms. -(KOENIGS, C. D. F.; KLARE, H. F. T.; OESTREICH*, M.; Angew. Chem., Int. Ed. 52 (2013) 38, 10076-10079, http://dx.