ChemInform Abstract: CF₃‐Carbenoid C—H Functionalization of (Hetero)arenes under Chelation‐Controlled Rh^III Catalysis.

Abstract

CF 3-Carbenoid C-H Functionalization of (Hetero)arenes under Chelation--Controlled Rh III Catalysis. -An efficient method for the Rh(III)-catalyzed CF3--carbenoid C-H functionalization of benzenes and indoles bearing a directing group is presented. The regioselectivity can be switched by changing the catalytic system. -(IAGAFAROVA, I. E.; VOROBYEVA, D. V.; PEREGUDOV, A. S.; OSIPOV*, S. N.; Eur. J. Org. Chem. 2015, 22, 4950-4955, http://dx.