ChemInform Abstract: EINSATZ DES MASSENSPEKTROMETERS BEI DER AUFKLAERUNG DER STRUKTUR VON ORGANOMETALL‐KOMPLEXEN, UNTERSUCHUNG ZWEIER NEUER CARBONYL‐CLUSTER DES KOBALTS SCO4(CO)9(P(CH3)2)2 UND S2CO3(CO)7P(CH3)2
Abstract:Dikobaltoctacarbonyl (I) reagiert mit Tetramethylbiphosphin‐disulfid (II) in Chloroform bei Raumtemperatur innerhalb von 2 Tagen zu den beiden neuen Kobalt‐Clustern (III) und (IV), deren Trennung chromatographisch gelingt.
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