ChemInform Abstract: Intramolecular Radical Cyclization of Silylacetylenic or Olefinic . alpha.‐Iodo Ketones: Application to the Total Synthesis of (.+‐.)‐ Modhephene.

Abstract

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Study on Debenzylation of Pentabenzylpentaza[3,3,3]Propellane

“…The requirements of density and energy level are the ideal framework structure of energetic compounds. [31][32][33][34][35][36] In 2014, Shreeve et al [37] first reported Polynitropentaza [3,3,3]propellane energetic materials' theoretical results, which indicated that the aza [3.3.3] propellane-containing energetic compounds may become the important high energy density Energy compounds. [38] In 2018, Lee et al [39] reported a simple yet highly efficient protocol for the synthesis of the hexaaza [3.3.3]propellane skeleton as a building block for high energy materials.…”