ChemInform Abstract: Lewis Acid Catalyzed [1,3]‐Sigmatropic Rearrangement of Vinyl Aziridines.

Abstract

Pyrrole derivatives R 0120 Lewis Acid Catalyzed [1,3]-Sigmatropic Rearrangement of Vinyl Aziridines. -The reaction of various mono-, disubstituted and fused aziridines allows an easy access to 3-pyrrolines and complex bicyclic systems. High functional group tolerance is shown. -(BRICHACEK, M.; LEE, D.; NJARDARSON*, J. T.; Org. Lett. 10 (2008) 21, 5023-5026; Dep. Chem. Chem. Biol., Cornell Univ., Ithaca, NY 14853, USA; Eng.) -R. Steudel 12-126