Chemischer Informationsdienst
 1984
DOI: 10.1002/chin.198410280
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ChemInform Abstract: METAL COMPLEXES WITH TETRAPYRROLE LIGANDS. XXXII. IMPROVED PROCEDURE FOR INSERTION OF OSMIUM INTO PORPHYRINS, CARBONYLOSMIUM(II) COMPLEXES OF MESOPORPHYRIN IX

Johann W. Buchler1,
Gerhard Herget2,
K. Oesten3

Abstract: Durch Reaktion von meso‐Tetra‐p‐tolyl‐porphyrin mit K‐hexachloroosmat (IV) in Diethylenglykolmonomethylether (andere Lösungsmittel sind nicht geeignet) gelang die Darstellung von Carbonyl‐Os(II)‐Komplexen des Porphyrins neben dem Dioxoosmium‐Komplex des Liganden.

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