Chemischer Informationsdienst
 1984
DOI: 10.1002/chin.198402246
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ChemInform Abstract: METHYLENEDIMAGNESIUM DIBROMIDE AS PRECURSOR OF METAL CARBENE COMPLEXES; PREPARATION OF TITANACYCLOBUTANES

J. W. BRUIN1,
G. Schat2,
Otto S. Akkerman3
et al.

Abstract: Die aus Methylenbromid (I) erhaltene Bis‐grignard‐Verbindung (II) reagiert mit Dicyclopentadienyl‐titandichlorid zu einer Zwischenstufe (IV), die mit Diphenylacetylen (V) oder mit Olefinen (VII) zu den Titana‐cyclobutanen (VI) bzw. (VIII) führt.

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