ChemInform Abstract: Michael Addition of Malonic Esters to endo‐Tricyclo[5.2.1.0^2,6]deca‐4,8‐dien‐4‐bromo‐3‐one: A Novel Entry to Highly Functionalized cis—anti—cis Fused Triquinane Framework/Skeleton.

Abstract

Depending on the conditions the reaction of substrate (I) with malonic esters (II) provides Michael adducts (III) or unexpected compounds (IV) as main or single product.