ChemInform Abstract: Modular Stereoselective Synthesis of (1→2)‐C‐Glycosides Based on the sp²—sp³ Suzuki—Miyaura Reaction.

Abstract

Suzuki-Miyaura Reaction. -The key step comprises a Ni-catalyzed cross-coupling reaction of D-glucal pinacol boronate with alkylbromide or alkyliodide glycoside, thus representing the first example for a challenging sp 2 -sp 3 cross-coupling in carbohydrate chemistry. -(OROSZOVA, B.; CHOUTKA, J.; POHL, R.; PARKAN*, K.; Chem. -Eur. J. 21 (2015) 19, 7043-7047, http://dx.