ChemInform Abstract: Neutral Mono‐ and Dipodands with Terminal Phosphinoylphenyl Groups.

Abstract

ChemInform Abstract The o-phosphinoylphenolates (I) are coupled with the tosylates (II) and (IV) or the bis(chloromethyl)phosphine oxide (VI) to give the dipodands (III), (V), and (VII). The monopodands (IX) and (XI) are prepared from (Ib) and the bromohydrin (VIII).

“In Silico” Design of New Uranyl Extractants Based on Phosphoryl-Containing Podands: QSPR Studies, Generation and Screening of Virtual Combinatorial Library, and Experimental Tests

“…Tris{[o-di(p-tolyl)phosphinyl]phenoxy}phosphine oxide (compound 1, Table 9). To a suspension of 3.223 g (0.010 mmol) of o-diphenylphosphinylphenol 45 and 3.260 g (0.010 mmol) of anhydrous Cs 2 CO 3 in 50 mL of anhydrous dioxane was added 0.65 g (0.0033 mol) of tris(chlormethyl)phoshine oxide. The mixture was heated to 95-101 °C for 24 h. After cooling to room temperature 150 mL of H 2 O was added, and then 6 N HCl was added until pH 1 was reached.…”

“…The residue was purified by column chromatography [SiO 2 /CHCl 3 , CHCl 3 -EtOH(20:1)] to yield 1.80 g (52%) (comp. 9) was obtained analogous to the compound 1 from 2.543 g (0.010 mmol) of dibutylphosphinylphenol, 45 3.260 g (0.010 mmol) of anhydrous Cs 2 CO 3 , and 0.65 g (0.0033 mol) of tris(chlormethyl)phoshine oxide in 50 mL of anhydrous dioxane. Yield Diphenylphosphinoyl-[(2-diphenylphoshinoyl-4-tert-butyl)-phenoxy}methan (compound 8, Table 9) was obtained analogously to compound 1 (Table 9) from 3.500 g (0.010 mmol) of 2-diphenylphosphinoyl-4-tert-butylphenol, 45 9) have been performed using the same protocol as used for the parent set of 32 compounds in ref 15.…”

Modified methods to synthesize of 1,8-bis[2-(diphenylphosphoryl)phenoxy]-3,6-dioxaoctane (L). Crystal structure and vibration spectra of [LiL]ClO4·2C6H6

“…A suspension of 1.4 g (32.7 mmol) of NaH in vaseline oil was added to a suspension of 9.6 g (32.7 mmol) of 2-(diphenylphosphoryl)phenol [6] in 60 mL of anhydrous dioxane. The mixture was stirred for 0.5 h at 100°С.…”

“…For the first time, phosphoryl podand L was synthesized by the reaction of sodium 2-diphenylphosphoryl phenolate with triethylene glycol ditosylate in boiling dioxane [6] or DMF [7]. Podand L 1 was prepared by the analogous reaction of sodium diphenylphosphorylmethyl phenolate with triethylene glycol ditosylate in dioxane [8].…”

“…Lithium compounds are used as components of compact energy sources [1]; metal lithium is used as a coolant in nuclear reactors, and isotope 6 Li is the only industrial source of tritium which is necessary for thermonuclear energetics. Lithium salts are used in psychiatry for reductive therapy of manic states and prevention of bipolar affective (manic-depressive) disorders [2].…”