ChemInform Abstract: ON THE REGIOSELECTIVITY OF THE BECKMANN REARRANGEMENT OF CYCLOBUTANONES WITH O‐MESITYLENESULFONYLHYDROXYLAMINE. A CONVENIENT SYNTHESIS OF SUBSTITUTED OCTAHYDROCYCLOPENTA(B)PYRROLES
Abstract:Die Beckmann‐Umlagerung der aus den Bicycloheptanonen (I), (V) und (VIII) zugänglichen Mesitylensulfonyloxime führt zu den bicyclischen Lactamen (III) und (IV), (VI) und (VII) bzw. (IX), wobei die Cyclopentafblpyrrole bevorzugt gebildet werden.
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