ChemInform Abstract: PHOSPHORUS COMPOUNDS WITH UNUSUAL COORDINATION. 5. (3 + 2)‐ AS WELL AS (4 + 2)‐CYCLOADDITION REACTIONS TO A KINETICALLY STABILIZED PHOSPHAALKENE

Zurmuehlen, F.; Roesch, W.; Regitz, Manfred

doi:10.1002/chin.198547228

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Reactions With Phosphorus−metal Complexes2

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2002

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“…The 1:2 reaction between the phosphaalkene 686 and the substituted o -quinones 77 (R 1 = R 2 = Cl, Br; R 1 = t -Bu, R 2 = H) proceeds via [4 + 2]-cycloadducts to give the phosphoranes 687 …”

Section: Reactions With Phosphorus−metal Complexesmentioning

confidence: 99%

“…437 The 1:2 reaction between the phosphaalkene 686 and the substituted o-quinones 77 (R 1 ) R 2 ) Cl, Br; R 1 ) t-Bu, R 2 ) H) proceeds via [4 + 2]-cycloadducts to give the phosphoranes 687. 438 The very reactive phosphorus-metal complexes 688 4 ] in dichloromethane solution to yield the diamagnetic complex 689. 431,432 The molecular structure of 689 (R 1 ) R 2 ) Cl, M ) Pd) has been determined from X-ray analysis.…”

Section: Reactions With Phosphorus−metal Complexesmentioning

confidence: 99%

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