Chemischer Informationsdienst
 1980
DOI: 10.1002/chin.198046320
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ChemInform Abstract: PREPARATION AND ACID‐CATALYZED REARRANGEMENTS OF A STEROIDAL 1,4‐QUINOL

Thomas M. Zydowsky1,
Christopher E. Totten2,
David M. Piatak3
et al.

Abstract: Tl(ClO4)3‐Oxidation des Östratrienols (I) gibt das Chinol (II) (Diastereomerenpaar), dessen Behandlung mit HCl bzw. HBr und anschließender Acetylierung der intermediär gebildeten 1‐Hydroxy‐östratriene zu den 3‐Halogen‐1‐acetoxy‐Derivaten (IIIa) bzw. (IIIb) führt.

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