ChemInform Abstract: Preparation and Structure of (Ph3P)2N(WSF5).

Abstract

Preparation and Structure of (Ph3P)2N(WSF5).-The title compound (IV) is characterized by XRD (triclinic, P1, Z = 2). IR and Raman spectroscopic results as well as 19F NMR and XRD data are reported for (III) (tetragonal, I4). The considerable distortion of the WSF-5 anion is explained by the W=S π-bonding and the associated trans-effect. -(HILBERS, M.; LAEGE, M.; MATTES, R.; Inorg.