Chemischer Informationsdienst
 1981
DOI: 10.1002/chin.198116321
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ChemInform Abstract: PROCEDURE FOR THE SYNTHESIS OF 3‐AMINO‐2,3,6‐TRIDEOXYHEXOPYRANOSE α‐GLYCOSIDES FROM GLYCALS

Kurt Heyns1,
J. Feldmann2,
Doris Hadamczyk3
et al.

Abstract: Bei der Umsetzung von Tri‐O‐acetyl‐D‐glucal (I) mit ‐ NaN3 unter BF3 ‐Et2O‐Kata1yse bildet sich ein Gemisch aus den Anomeren (IIa) und (IIb), die mit ihren jeweiligen [3.3]‐sigmatropen Umlagerungsprodukten (IIIa) 141R bzw. (IIIb) im reversiblen Gleichgewicht stehen.

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