ChemInform Abstract: Rapid, Regioconvergent, Solvent‐Free Alkene Hydrosilylation with a Cobalt Catalyst.

Chen, Chi; Hecht, Maxwell B.; Kavara, Aydin; Brennessel, William W.; Mercado, Brandon Q.; Weix, Daniel J.; Holland, Patrick L.

doi:10.1002/chin.201613051

Cited by 2 publications

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“…In general, the hydrosilylation reaction is sensitive to the substitution of an alkene: terminal monosubstituted alkenes were found to be the most reactive, while internal and 1,1-gem double bonds are less prone to react. 73,74 Even selective hydrosilylation of monosubstituted alkenes in the presence of internal alkenes was reported. 75 Capitalizing on the high regio-selectivity of the hydrosilylation process we reacted the allyl group of DPE-All with PDMS-H while retaining 1,1-diphenylethylene functionality.…”

Section: Resultsmentioning

confidence: 99%

Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

et al. 2018

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Section: Resultsmentioning

confidence: 99%

Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

et al. 2018

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“…[219] More recently, the same group found NHC-ligated cobalt(II) amide complexes to be efficient for anti-Markovnikov hydrosilylation of terminal alkenes with tertiary silanes. [220] Several other cobalt catalysts were also developed in Holland group (88), [221] Chirik group (89), [222] Fout group (73), [223] Rauchfuss group (90) [224] and Pawlud group (91), [225] respectively.…”

Section: Co-catalyzed Hydrosilylation Of Alkenesmentioning

confidence: 99%

Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

2018

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Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl-or alkenyl-metal reagents, which have a wide range of applications in organic transformations. In recent years, the first row transition metals (such as copper, nickel, cobalt, iron, etc.) have emerged high activity and selectivity in this area with the aid of a variety of ligands. This review covers the recent advances in the hydrometallation of minimally functionalized unsaturated C-C bonds (including alkenes, alkynes, dienes, allenes, enynes, etc.), as well as transformations involving catalytic hydrometallation process via the first row transition metal catalysis.

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ChemInform Abstract: Rapid, Regioconvergent, Solvent‐Free Alkene Hydrosilylation with a Cobalt Catalyst.

Abstract: The utility of β‐diketiminate cobalt(I)‐arene complexes as catalyst for the hydrosilylation of terminal alkenes with phenylsilane and triethoxysilane is demonstrated.

Cited by 2 publications

References 1 publication

Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

Bulk and Surface Morphologies of ABC Miktoarm Star Terpolymers Composed of PDMS, PI, and PMMA Arms

Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

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