ChemInform Abstract: Regioselective Ring Opening of Chiral Epoxy Alcohols by Primary Amines.

Abstract

1992 cleavage reactions, decomposition reactions, pyrolysis cleavage reactions, decomposition reactions, pyrolysis O 0100 29 -070 Regioselective Ring Opening of Chiral Epoxy Alcohols by Primary Amines. -Titanium(IV)-mediated reaction of the chiral epoxides (I) with primary amines such as (II) yields 3-amino-1,2-diols such as (III) as the main or exclusive products. Further examples are given in the original paper. -(CANAS, M.; POCH, M.; VERDAGUER, X.; MOYANO, A.; PERICAS, M. A.; RIERA, A.; Tetrahedron Lett. 32 (1991) 47, 6931-6934; Dep. Quim. Org., Univ., 08028 Barcelona, Spain; EN)