ChemInform Abstract: Remote Functionalization of Hydrocarbons with Reversibility Enhanced Stereocontrol.

Abstract

Remote Functionalization of Hydrocarbons with Reversibility Enhanced Stereocontrol. -Heating in THF (step 2) is necessary for the isomerization of the intermediate allylzirconocene species into a single E-allylzirconocene that can be trapped by appropriate electrophiles to form internal E-olefins under high 1,4-diastereocontrol. -(VASSEUR, A.; PERRIN, L.; EISENSTEIN, O.; MAREK*, I.; Chem. Sci. 6 (2015) 5, 2770-2776, http://dx.