Chemischer Informationsdienst
 1984
DOI: 10.1002/chin.198447317
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ChemInform Abstract: RUTHENIUM COMPLEXES WITH DIAZABUTADIENES. 3. TRANS AND CIS ISOMERS OF DICHLOROBIS(DIAZABUTADIENE)RUTHENIUM (RN:CR′CR′:NR)2RUCL2

Heindirk tom Dieck1,
Wolfgang Kollvitz2,
I. + Kleinwaechter3

Abstract: Die ausgehend von (I) und entsprechenden Diiminen (II) dargestellten trans‐Komplexe (IIIa) und (II‐Ic) isomerisieren bei I30°C irreversibel zu den thermodynamisch stabileren cis‐Verbindungen (IV); (IIIb) reagiert auch bei längerem Erhitzen auf 160°C nicht.

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