ChemInform Abstract: Sc(OTf)3‐Catalyzed [3 + 3] Annulation of Cyclopropane 1,1‐Diesters with Mercaptoacetaldehyde: A Facile Strategy for the Synthesis of Tetrahydrothiopyranols.
Abstract:A Sc(OTf)3‐catalyzed formal [3 + 3] cycloaddition of cyclopropane dicarboxylates with mercaptoacetaldehyde is developed to produce tetrahydrothiopyranols in good yields.
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