ChemInform Abstract: Some Chemisty in the Li/“SOCl2 + BrCl” Cell

Abstract

Abstract(BCX cell).

Lithium-Conducting Polymer Electrolytes for Chemical Power Sources

“…The polymer electrolyte consisting of a blend of a poly[bis(methoxyethoxyethoxidophosphazene)] complex salt (I) and PEO (II), doped with LiCF 3 SO 3 or LiClO 4 , was cast from a solution of I + II in acetonitrile and vacuumdried at 100oC [51]. At a I : II ratio of 1 : 1, the specific conductivity of the electrolyte was 2 0 10 !4 (at 20oC) and 5 0 10 !2 S cm !1 (at 100oC).…”

Ionically Conductive Thin Polymer Films Prepared by Plasma Polymerization: V . Preparation and Characterization of Solid Polymer Electrolyte Composed of Plasma Polymerized Complex

“…On account of their relatively high ionic conductivities (i, 2), solid polymer electrolytes based on alkali metal salt complexes of polyethers [poly(ethylene oxide) and poly-(propylene oxide)] recently have received considerable attention as potential materials for use in electrochemical applications such as solid-state lithium batteries, sensors, and display devices (3)(4)(5)(6)(7)(8). The ionic conductivities of these solid polymer electrolytes are considerably lower than those of liquid electrolytes (9), typical values at room temperature being in the order of i0-8-i0 -6 S cm -1.…”