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“…19,20 Even for near-identical chemical composition, crystalline and amorphous compounds could exhibit completely different physicochemical properties such as solubility, conductivity, or adsorption. 33,34 Nevertheless, due to the lack of long-range order, the structure-property relationships in amorphous solid phases of TMPs are still relatively poorly explored in contrast to their crystalline counterparts.…”
Here, we describe how to synthesise proton-conductive transition metal phosphates (TMPs) by direct thermal processing of precursor M-struvites, NH4MPO4·6H2O, with M = Ni2+, Co2+. In the as-derived TMP phases their...
“…19,20 Even for near-identical chemical composition, crystalline and amorphous compounds could exhibit completely different physicochemical properties such as solubility, conductivity, or adsorption. 33,34 Nevertheless, due to the lack of long-range order, the structure-property relationships in amorphous solid phases of TMPs are still relatively poorly explored in contrast to their crystalline counterparts.…”
Here, we describe how to synthesise proton-conductive transition metal phosphates (TMPs) by direct thermal processing of precursor M-struvites, NH4MPO4·6H2O, with M = Ni2+, Co2+. In the as-derived TMP phases their...
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