ChemInform Abstract: Synthesis and Crystal Structure of a Stable S‐Nitrosothiol Bearing a Novel Steric Protection Group and of the Corresponding S‐Nitrothiol.

Abstract

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Conformational Properties of Ethyl- and 2,2,2-Trifluoroethyl Thionitrites, (CX3CH2SNO, X = H and F)

“…18,19 Few other experimentally determined structures can be found in the literature. [19][20][21] In general it was assumed that -mainly due to sterical reasons -tertiary thionitrites prefer the anti conformation, whereas the syn form is adopted by primary derivatives. However, a delicate balance between both steric and electronic effects are known to affect the conformational behavior.…”