ChemInform Abstract: Synthesis and Reactions of Oximino Derivatives of Acylferrocenes with Electron Donor Substituents in β‐Position.

Abstract

Synthesis and Reactions of Oximino Derivatives of Acylferrocenes with Electron Donor Substituents in β-Position.-Nitrosation of the acylferrocenes (I) gives the oximes (III) via the corresponding nitroso compounds. The oximes (III) are converted to the derivatives (V), (VII), and (X). Treatment of the diacetylglyoxime (X) with alkali results in cyclization, producing the oxadiazolylferrocene (XI). -(POLYAKOV, B. V.; TVER-DOKHLEBOV, V. P.; TSELINSKII, I. V.; Zh.