ChemInform Abstract: SYNTHESIS AND STRUCTURE OF DINUCLEAR NIOBIUM AND TANTALUM COMPLEXES CONTAINING AN UNUSUAL BRIDGING LIGAND DERIVED FROM ACETONITRIL
Abstract:Nb‐ bzw. Ta‐tetrachlorid und Acetonitril reagieren in Gegenwart von Zn‐Granulat zu Trichloro‐tris‐[acetonitril]‐Metallverbindungen, die nach IR‐Daten als Dimere (I) vorliegen, bei denen vier Acetonitrilmoleküle und ein neuer von Acetonitril abgeleiteter Ligand über N an die Metalle koordiniert sind.
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