ChemInform Abstract: Synthesis and Structure of N‐(Silylalkyl)amides: Rhodium‐Catalyzed Hydrosilylation of Enamides.

Abstract

Synthesis and Structure of N-(Silylalkyl)amides: Rhodium-Catalyzed Hydrosilylation of Enamides.-A new synthesis of title compounds by Rh-catalyzed hydrosilylation of olefins attached to N-, O-, and S-containing functional groups is presented. The reaction course of vinyl carboxylates, thiocarboxylates, vinyl ethers and vinyl sulfides is highly dependent on the substrates, catalysts and solvents. -(MURAI, T.; KIMURA, F.; TSUTSUI, K.; HASEGAWA, K.; KATO, S.; Organometallics 17 (1998) 5, 926-932; Dep.