ChemInform Abstract: Synthesis of Z‐Alkenes from Rh(I)‐Catalyzed Olefin Isomerization of β,γ‐Unsaturated Ketones.

Abstract

Synthesis of Z-Alkenes from Rh(I)-Catalyzed Olefin Isomerization of β,γ-Unsaturated Ketones. -The title synthesis is applicable for a broad range of aromatic and aliphatic substituted ketones. The substrates (IX) and (X) are ineffective in this reaction. -(ZHUO, L.-G.; YAO, Z.-K.; YU*, Z.-X.; Org. Lett. 15 (2013) 18, 4634-4637, http://dx.