ChemInform Abstract: Tandem Radical Cyclization Reaction of N‐Aziridinyl Imines to (3.3.3) Propellanes: Formal Total Syntheses of dl‐Modhephene.

Abstract

Tandem Radical Cyclization Reaction of N-Aziridinyl Imines to (3.3.3) Propellanes: Formal Total Syntheses of dl-Modhephene.-The first synthesis of propellane rings via tandem radical cyclization reactions is described. This strategy is applied to the synthesis of the precursors (VIII) and (XIII) of modhephene (XIV). -(LEE, H.-Y.; KIM, D.-I.; KIM, S.; Chem.