ChemInform Abstract: The Exchange Reactions of Tetrathiophosphates with Thiophosphoryl Chloride.

Abstract

The Exchange Reactions of Tetrathiophosphates with Thiophosphoryl Chloride.-Thermal reaction of tetrathiophosphates (I) and (IV) with thiophosphoryl chloride proceeds via exchange of alkyl(aryl)thio groups between the tetracoordinated phosphorus compounds. Depending on the ratio of reactants, one or two alkyl(aryl)thio groups are substituted. -(KHOKHLOV, P. S.; SOKOLOVA, G. D.; OSIPOV, V. N.; SAVENKOV, N. F.; Izv.