ChemInform
 2015
DOI: 10.1002/chin.201501050
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ChemInform Abstract: Urea‐Induced Acid Amplification: A New Approach for Metal‐Free Insertion Chemistry.

Erica D. Couch
1
,
Tyler J. Auvil
2
,
Anita E. Mattson
3

Abstract: A difluoroboronate substituted urea is shown to be an efficient catalyst for O—H and S—H insertion reactions of α‐aryldiazoacetates to produce a wide variety of α‐acyloxyesters and α‐mercaptoesters, respectively.

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