Abstract:Micellar photocatalysis has recently provided new opportunities for the activation of strong carbon chlorine bonds and enabled the valorization of cheap and readily available chlorinated starting materials. Thus far, however, it has mainly explored strongly reducing conditions, which restrict the available chemical space to radical or anionic reactivity. Here, we demonstrate a radical-polar crossover process involving cationic intermediates, which enable chemodivergent functionalization of chlorinated benzamid… Show more
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