Chiral Alkoxy Side Chains from (‐)‐Amino Acids in Mediating Asymmetric Synthesis of Tricarbonyl(cyclohexadienyl)iron Complexes

Chang, Tsu‐Hsin; Kuo, Chien‐Ren; Ong, Chi Wi

doi:10.1002/jccs.199700076

Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Paley¹

2005

Encyclopedia of Inorganic Chemistry

2

0

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Studies involving the preparation, reactivity, and properties of the organometallic complexes of iron (compounds possessing a FeC bond) have played a central role in the growth of organometallics as a major subdiscipline with chemistry. From the discovery of ferrocene in the 1950s to the present day, interest and research activity remain high. This entry provides a survey of this large and diverse area of organometallic chemistry, and is arranged by increasing hapticity of the organic ligand of interest that is bound to iron. Included are discussions of the chemistry of iron σ‐alkyl, acyl, alkynyl, and vinyl complexes, iron carbenes, η1‐ and η3‐allyl iron complexes, η2‐alkene and η4‐diene iron complexes, trimethylenemethane and cyclobutadiene complexes of iron, cationic iron pentadienyl, cyclohexadienyl, and arene complexes, and ferrocenes and heteroferrocenes.

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Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Paley

¹

2005

Encyclopedia of Inorganic and Bioinorganic Chemistry

1

0

View full text Add to dashboard Cite

Studies involving the preparation, reactivity, and properties of the organometallic complexes of iron (compounds possessing a FeC bond) have played a central role in the growth of organometallics as a major subdiscipline with chemistry. From the discovery of ferrocene in the 1950s to the present day, interest and research activity remain high. This entry provides a survey of this large and diverse area of organometallic chemistry, and is arranged by increasing hapticity of the organic ligand of interest that is bound to iron. Included are discussions of the chemistry of iron σ‐alkyl, acyl, alkynyl, and vinyl complexes, iron carbenes, η1‐ and η3‐allyl iron complexes, η2‐alkene and η4‐diene iron complexes, trimethylenemethane and cyclobutadiene complexes of iron, cationic iron pentadienyl, cyclohexadienyl, and arene complexes, and ferrocenes and heteroferrocenes.

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Asymmetric Synthesis of a New Salen Type‐titanium Complex as the Catalyst for Asymmetric Trimethylsilylcyanation of Aldehydes

Lin

¹

,

Chen

²

2010

J Chinese Chemical Soc

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Chiral Alkoxy Side Chains from (‐)‐Amino Acids in Mediating Asymmetric Synthesis of Tricarbonyl(cyclohexadienyl)iron Complexes

Cited by 4 publications

References 8 publications

Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Asymmetric Synthesis of a New Salen Type‐titanium Complex as the Catalyst for Asymmetric Trimethylsilylcyanation of Aldehydes

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