Chitosan tailor-made membranes as biopolymeric support for electromembrane extraction

Román-Hidalgo, Cristina; López-Pérez, G.; Martín-Valero, María Jesús; Bello‐López, Miguel Ángel

doi:10.1016/j.talanta.2019.02.079

Cited by 27 publications

(8 citation statements)

References 29 publications

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“…EFs for parabens and FQs were as expected, while none of the NSAIDs were extracted. Those results agree with previously reported optimal conditions for the EME of this drug family [ 19 ].…”

Section: Resultssupporting

confidence: 93%

“…As has been discussed previously, the most important experimental parameters controlling EME procedures are pH, the volumes of the donor and acceptor phases, applied voltage, stirring speed, as well as extraction time. In previous work using this same kind of EME device [ 10 , 19 , 21 ], optimum volumes for both phases were settled, being 10 mL for donor solution and 50 µL for acceptor solution, as determined by the shape and size of the EME device. In addition, 600 rpm was fixed as the maximum stirring speed, to avoid vortices in the donor solution.…”

Section: Resultsmentioning

confidence: 99%

“…This feature makes chitosan a very versatile raw material that allows the synthesis of tailor-made membranes aimed at the selective extraction of targeted analytes. Indeed, chitosan films have already been successfully used in different EME procedures for the extraction and determination of NSAIDs and polar acidic drugs [ 19 ], as well as for the selective extraction of FQs from urine samples [ 10 ]. Regarding paraben compounds, the versatile chemical structure of chitosan has been exploited for the fabrication of a novel molecularly imprinted biomembrane, capable of cleaning and isolating paraben families from complex matrices by means of advanced matrix solid-phase dispersion [ 20 ].…”

Section: Introductionmentioning

confidence: 99%

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Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films

et al. 2023

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A chitosan biopolymeric membrane was successfully used as a support in a green electromembrane extraction procedure for the simultaneous and selective extraction of seven parabens and three fluoroquinolones in the presence of three non-steroidal anti-inflammatory drugs. The optimal experimental conditions (10 mL donor phase and 50 μL acceptor phase, pH 10 in both phases; 80 V of applied voltage during 15 min of extraction time) were determined, providing high enrichment factors for six of the studied parabens (EF ≥ 90) and the three fluoroquinolones (EF ≥ 50). Wide linear concentration ranges (0.5–500 μg L−1), good linearity (>97%), low limits of detection (0.2–1.1 μg L−1), and good repeatability (relative standard deviation values 4–10%) were achieved. The proposed method was successfully applied for the extraction of the target analytes from different kinds of water samples (river, lake, and swimming pool). The usage of a chitosan membrane in the extraction process presents many advantages, as it is a biodegradable and versatile support, offering a good alternative to commercial plastic materials commonly used in this methodology and these procedures.

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“…EFs for parabens and FQs were as expected, while none of the NSAIDs were extracted. Those results agree with previously reported optimal conditions for the EME of this drug family [ 19 ].…”

Section: Resultssupporting

confidence: 93%

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films

et al. 2023

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“…Chitosan is moisture sensitive in nature. 122 Water exists in three forms in swollen chitosan: free water (freezing water), bound water (non-freezing water) and freezing bound water. Bound water corresponds to the water molecules that are introduced during the initial swelling, and which disrupt the intermolecular hydrogen bonds of chitosan, subsequently binding to the polymer's hydrophilic sites.…”

Section: Moisture Retention Abilitymentioning

confidence: 99%

Perspectives for chitosan‐based membranes in CO₂/N₂ separation : Structure‐property relationship

Borgohain

2021

Greenhouse Gases

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Extensive research has been conducted on a variety of processes for abating the increasing CO 2 emissions which have been causing adverse effects on the environment. Among these, gas separation membranes have the potential to overcome a number of limitations of existing technologies by reducing the cost of operations and providing an efficient, compact module which can be employed for separating CO 2 from natural gas and post-combustion flue gas streams. Recently, chitosan and its derivatives have proven their ability to form CO 2 -selective facilitated transport membranes through the utilization of the amino group fixed site carriers present in the polymer. Later, the performance of chitosan membrane can be substantially improved by carrier enrichment. This review aims to cover the structure-property relations of chitosan and its film-forming derivatives, with a brief discussion of the advantages and challenges in using these polymers.

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“…After these membranes become infused with organic solvents, PIMs act as SLMs for the extraction of basic drugs [17], acidic drugs [15], and herbicides [16]. In addition, polyacrylonitrile (PAN)/polydimethylsiloxane (PDMS) membranes [18], chitosan membranes [19], and polyvinylidene difluoride (PVDF) membranes [20,21] have been proposed as supports to extract phthalate compounds, acidic drugs, and peptides.…”

Section: Introductionmentioning

confidence: 99%

Nylon Membrane-Based Electromembrane Extraction Coupled with Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry for the Determination of Insulin

et al. 2022

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A rapid and sensitive protein determination method that uses electromembrane extraction (EME) and is coupled with matrix-assisted laser desorption/ionization mass spectrometry (MALDI/MS) is developed. A flat nylon membrane is used to collect proteins from an aqueous solution and is directly analyzed by MALDI/MS after the addition of the MALDI matrix. Insulin is used as a model protein to investigate the optimum extraction of the parameters. The optimum EME conditions are obtained at 12 V of voltage, 10 min of extraction time, 12 mL sample volume, and 400 rpm agitation rate. The linear dynamic range (LDR) of insulin in an aqueous solution is in the range of 1.0–100.0 nM. The limit of detection (LOD) for insulin in an aqueous solution is 0.3 nM with 103-fold signal-to-noise (S/N) ratio enhancement. Furthermore, the applicability of this method to determine insulin in complicated sample matrices is also investigated. The LDR of insulin in human urine samples is in the range of 5.0–100.0 nM, and the LOD of insulin in urine samples is calculated to be 1.5 nM. The precision and accuracy of this method are evaluated at three different concentration levels, and the coefficient of variation (CV) and relative error are less than 6%. This approach is time-efficient and economical, as the flat membrane mode of EME coupled with MALDI/MS is suitable.

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Chitosan tailor-made membranes as biopolymeric support for electromembrane extraction

Cited by 27 publications

References 29 publications

Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films

Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films

Perspectives for chitosan‐based membranes in CO₂/N₂ separation : Structure‐property relationship

Nylon Membrane-Based Electromembrane Extraction Coupled with Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry for the Determination of Insulin

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Chitosan tailor-made membranes as biopolymeric support for electromembrane extraction

Cited by 27 publications

References 29 publications

Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films

Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films

Perspectives for chitosan‐based membranes in CO2/N2 separation : Structure‐property relationship

Nylon Membrane-Based Electromembrane Extraction Coupled with Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry for the Determination of Insulin

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Product

Resources

About

Perspectives for chitosan‐based membranes in CO₂/N₂ separation : Structure‐property relationship