Chromium-substituted aluminophosphate-5: a recyclable catalyst for the selective oxidation of secondary alcohols

A Two-Dimensional Mixed-Metal Phosphate Templated by Ethylene Diamine, [enH2][CoIn(PO4)2H(OH2)2F2]

“…One particular goal is the incorporation of active metals into known microporous phases to modify their catalytic behavior. The transition-metal substituted aluminophosphates CoAPO-18 (1) and are successful examples of this approach.…”

Surface Chemistry and Spectroscopy of Chromium in Inorganic Oxides

“…Other important catalytic activities are hydrogenation-dehydrogenation, oxidation, isomerization, aromatization, and DeNO x reactions. [14][15][16][17][18][19][20][21][22][23][24][25][26][27][28] The basis for the activity of Cr in such a wide spectrum of reactions lies in the variability of oxidation states, of coordination envi-ronments, and of degree of polymerization of Cr oxide species. This variability is especially pronounced on the surface.…”

Study on Chromium‐Containing Aluminophosphate CrAPO‐5 via Density Functional Theory

“…[2][3][4][5] Chromium-containing aluminophosphate-5 molecular sieve (CrAPO-5) is an active catalyst for selective oxidation reaction in liquid phase. [6][7][8][9] Its catalytic properties were thought to be derived from redox centers of chromium ions in the aluminophosphate-5 (AFI) framework. 10 As a result, characterization of the local structure of chromium ions in CrAPO-5 is important.…”