2023
DOI: 10.1002/chem.202303339
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Classical Gold Carbonyl Complexes in Tetrahedral and Trigonal‐Planar Settings

Mukundam Vanga,
Alvaro Muñoz‐Castro,
H. V. Rasika Dias

Abstract: A unique four‐coordinate, classical gold(I)‐carbonyl complex with substantial backdonation from gold has been isolated by using a B‐methylated and fluorinated tris(pyridyl)borate chelator. Its lighter silver(I) and copper(I) analogs enabled a study of trends in the coinage‐metal family. The B‐arylated ligand version also afforded a gold–carbon monoxide complex that displays a notably low C−O stretch value, but with trigonal planar geometry at the gold. A computational analysis shows that the AuI−CO bonds of th… Show more

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