2020
DOI: 10.1063/1.5128120
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Clean, robust alkali sources by intercalation within highly oriented pyrolytic graphite

Abstract: We report the fabrication, characterization, and use of rubidium vapor dispensers based on highly-oriented pyrolytic graphite (HOPG) intercalated with metallic rubidium. Compared to commercial chromate salt dispensers, these intercalated HOPG (IHOPG) dispensers hold an order of magnitude more rubidium in a similar volume, require less than one-fourth the heating power, and emit less than one-half as many impurities. Appropriate processing permits exposure of the IHOPG to atmosphere for over ninety minutes with… Show more

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Cited by 13 publications
(8 citation statements)
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“…When the dispenser is turned back on, there is a spike in background pressure: this effect has been noted by others, and is likely due to a release of gas from both the chamber walls and the dispenser material as the dispenser temperature increases. [24] After some time, the pressures return to their values prior to the cycling experiment.…”
Section: Resultsmentioning
confidence: 99%
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“…When the dispenser is turned back on, there is a spike in background pressure: this effect has been noted by others, and is likely due to a release of gas from both the chamber walls and the dispenser material as the dispenser temperature increases. [24] After some time, the pressures return to their values prior to the cycling experiment.…”
Section: Resultsmentioning
confidence: 99%
“…The dispenser requires 2.15 A current to maintain optimal conditions, or 2.22 W of power. Continued investigation is required to develop techniques to achieve substantially reduced power consumption while maintaining the appropriate alkali [24,25] and background pressures.…”
Section: Discussionmentioning
confidence: 99%
“…The vacuum cell's 25 × 4.0 × 3.2 cm 3 volume could be substantially reduced if the redundant ion pump (the only magnetic component) is removed. This vacuum cell with no active pumping, ≈ 10 −6 mbar pressures and projected helium-limited lifetime of several years will be enhanced in future via a new generation of 'cleaner' atomic reservoirs [34][35][36] .…”
mentioning
confidence: 99%
“…A different rubidium source would ameliorate the situation, e.g. lower temperature methods include capturing Rb in graphite, for either thermal 34 or electronic release 35 . Microfabrication-based beam options are also now available 36 .…”
mentioning
confidence: 99%
“…To date, the clock stability limitation at 1 day on this setup is suspected to come from a possible unstable cell inner atmosphere. This could be related to Ne buffer gas permeation through the glass windows 36 , materials degassing, or dispenser pollution 37 .…”
mentioning
confidence: 99%