; this leads to an unanswered question of how could the early Martian atmosphere has maintained a greenhouse effect sufficient to allow for water on the surface present as a liquid? Previous studies have suggested the possibility of hydrogen as a greenhouse gas (Pierrehumbert & Gaidos, 2011; Sagan, 1977); Ramirez et al. (2014) proposed the idea that collision-induced absorption (CIA) between carbon dioxide (CO 2) and hydrogen gas (H 2) from volcanic events could provide the additional atmospheric absorption needed to trap enough radiation to raise the ancient Martian surface temperature above freezing. However, there were no measured CO 2-H 2 CIA cross sections available in the literature at the time of Ramirez et al. (2014), so N 2-H 2 was used as a proxy, although they had argued that CO 2-H 2 CIA should be even stronger. This was followed up in a study by Wordsworth et al. (2017), wherein they simulated the CIA of CO 2-H 2 and CIA of CO 2 and methane (CH 4), and their simulations did show that CO 2-H 2 CIA was stronger than N 2-H 2 CIA. Wordsworth et al. (2017) derived their CIA by performing ab initio calculations of the zeroth spectral moment of a CO 2-H 2 /CH 4 system, and then approximating the spectral shape as a linear combination of CO 2-CO 2 and H 2-H 2 or CH 4-CH 4 CIAs with the weighting determined by a combination of the ab initio calculation and adjusting the relative values to reproduce N 2-H 2 and N 2-CH 4 CIA spectra. The theoretical cross sections from Wordsworth et al. (2017) have strong absorption features in the range of 0-600 cm −1 and 1,200-1,500 cm −1 for CO 2-CH 4 ; for CO 2-H 2 , absorption was predicted to be a broad feature over the range of 0-1,500 cm −1. While this approximation appears to give accurate results, there can be significant deviations. For example, for CO 2-CH 4 above 1,000 cm −1 , there are