CO<sub>2</sub>reduction reactions: general discussion

North, Michael S.; Abrantes, Pedro; Remiezowicz, Eryk; Bardow, André; Dodson, Jennifer R.; Manning, Troy D.; Albo, Jonathan; Reed, Daniel M.; Harris, D. Kenwin; Ingram, Ian; Cowan, Alexander J.; Moss, Matthew; Carrera, Gonçalo V. S. M.; Foote, Alexander; Fraga, Eric S.; Styring, Peter; Bogaerts, Annemie; Centi, Gabriele; Navarrete, Alexander; Comerford, James W.; Dowson, George; Coogan, Anthony; Butterworth, Thomas; Lamb, Katie J.; Aresta, Michele; Janáky, Csaba; Heyn, Richard; Webb, William; Rooij, G.J. van; Meine, Niklas; Meynen, Vera; Michez, Roman; Churina, Dina; Dossumov, K.; Du, Xian; Spooren, Jeroen; Herskowitz, M.; Michiels, Koen; Capacchione, Carmine

doi:10.1039/c5fd90080h

Cited by 6 publications

(4 citation statements)

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“…It contains properties of both types of plasma and is characterized by both high electron density and a high degree of non-equilibrium. Bogaerts and Centi describe this type of plasma as very promising for CO 2 conversion due to its high process flexibility, which allows different types of reactions to be carried out (e.g., pure CO 2 splitting, as well as CO 2 conversion in the presence of CH 4 , H 2 , or H 2 O [15][16][17]).…”

Section: Plasma-based Co 2 Splitting-a Short Reviewmentioning

confidence: 99%

Techno-Economic Potential of Plasma-Based CO2 Splitting in Power-to-Liquid Plants

et al. 2023

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Mitigating climate change requires the development of technologies that combine energy and transport sectors. One of them is the production of sustainable fuels from electricity and carbon dioxide (CO2) via power-to-liquid (PtL) plants. As one option for splitting CO2, plasma-based processes promise a high potential due to their flexibility, scalability, and theoretically high efficiencies. This work includes a modeling and techno-economic analysis. A crucial element is the process of the joint project PlasmaFuel, in which two plasma technologies are included in a PtL plant to produce synthetically sulfur-free marine diesel. The results are divided into three scenarios, which differ in the use of different boundary conditions and thus represent different degrees of technology development. The evaluation results in process efficiencies from 16.5% for scenario 2018/20 to 27.5% for scenario 2050, and net production costs between EUR 8.5/L and EUR 3.5/L. Furthermore, the techno-economic potential is mapped in order to open up development steps in the direction of costs below EUR 2.0/L. The present work allows statements regarding system integration and the industrial use of the plasma-based process.; moreover, conclusions can be drawn towards the most important levers in terms of process optimization.

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Section: Plasma-based Co 2 Splitting-a Short Reviewmentioning

confidence: 99%

Techno-Economic Potential of Plasma-Based CO2 Splitting in Power-to-Liquid Plants

et al. 2023

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“…Тем не менее, большинство исследователей почему-то предпочитают использовать именно эти ферменты, и число публикаций по фиксации углекислого газа с использованием FDH составляет десятки (если не сотни) в год. Для понимания проблемы можно найти множество обзоров на эту тему (некоторые обзоры, наиболее интересные, с нашей точки зрения, представлены здесь) [106][107][108][109][110][111][112][113][114][115][116][117][118][119][120][121]. В качестве источников энергии некоторые авторы предлагают использовать элек-тричество, однако для фиксации углекислого газа в заявляемых объемах электричества надо очень много, а оно в современных условиях совсем не дешево, и почему-то мало кто вспоминает, что для этого нужна вода, а проблема чистых источников воды в ближайшем будущем должна стать даже более важной, чем энергетическая.…”

Section: гибридные биокатализаторы с регенерацией Nad(p)h на основе ф...unclassified

Formate Dehydrogenase: From Nad(p)h Regeneration To the Target in Pathogens Biofilms, a Component Of Highly Efficient Hybrid Biocatalysts and Co2 Fixation From the Atmosphere

Tishkov,

Pometun,

Savin

2023

Lomonosov Chemistry Journal

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NAD(P)+ -dependent formate dehydrogenase (EC 1.2.1.2, FDH) catalyzes the simple from chemical and biological point of view reaction of formate ion oxidation to carbon dioxide with corresponding reduction of NAD(P)+ to NAD(P) H. Advances in the life sciences have shown that this reaction plays an extremely important role in a wide variety of organisms. The areas and types of practical applications of FDH are also permanently expanding. In this review we considered the main stages in the development of understanding and knowledge about the role of formate dehydrogenase in living systems. Achievements in creation of highly effi cient catalysts based on FDH for classic biotechnology as well as for new areas are also considered. The importance of appropriate choice of the initial FDH for the creation of a biocatalyst with the required and prescribed properties with minimal costs is shown. The prospects for the use of FDH for the fixation of CO2 are discussed.

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“…24 There remains a lack of insight into the plasma environment, with the chemical effects yet to be understood. 46 This can be attributed to, at least partially, the correlation between physical and chemical effects introduced in a packed bed, which makes distinguishing the impacts difficult. 46 What is clear, however, is that the current exploratory approach, where the most thermally active nickel-based materials (on alumina or ceria supports) are assumed to be the best for plasma catalysis, requires greater thought given the distinctly different reaction environment in plasma discharges.…”

Section: ■ Capturing Energy: Hybrid Systemsmentioning

confidence: 99%

“…We emphasize that it is not yet possible to recommend an “ideal” catalyst for plasma-catalytic applications, and further detailed studies are vital . There remains a lack of insight into the plasma environment, with the chemical effects yet to be understood . This can be attributed to, at least partially, the correlation between physical and chemical effects introduced in a packed bed, which makes distinguishing the impacts difficult .…”

Section: Capturing Energy: Hybrid Systemsmentioning

confidence: 99%

Two Steps Back, One Leap Forward: Synergistic Energy Conversion in Plasmonic and Plasma Catalysis

et al. 2021

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Hybrid catalytic systems are poised to maximize the efficiency of energy conversion. When coupling heat with visible light or plasma sources, known thermally active catalysts are commonly used. The question becomes whether adapting thermally activated catalysts to hybrid energy systems is the ideal strategy. Differences in reaction pathways, including how the energy is exchanged within hybrid systems, mean new catalyst design approaches are needed. To enable a leap forward in designing hybrid systems and accelerate effective plasma/light catalyst development, there is a need to take two steps back to (i) revise the current strategies used to design appropriate catalysts and (ii) identify the criteria critical to regulating system behavior. Spotlighting carbon dioxide valorization, current routes to catalyst design for hybrid systems are evaluated. As these systems are playing an ever-increasing role in a clean energy future, catalyst design strategies involving ongoing retrospection and realignment toward prevailing energy coupling/conversion mechanisms are discussed to facilitate the leap forward.

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CO₂reduction reactions: general discussion

Cited by 6 publications

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Techno-Economic Potential of Plasma-Based CO2 Splitting in Power-to-Liquid Plants

Techno-Economic Potential of Plasma-Based CO2 Splitting in Power-to-Liquid Plants

Formate Dehydrogenase: From Nad(p)h Regeneration To the Target in Pathogens Biofilms, a Component Of Highly Efficient Hybrid Biocatalysts and Co2 Fixation From the Atmosphere

Two Steps Back, One Leap Forward: Synergistic Energy Conversion in Plasmonic and Plasma Catalysis

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CO2reduction reactions: general discussion

Cited by 6 publications

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Techno-Economic Potential of Plasma-Based CO2 Splitting in Power-to-Liquid Plants

Techno-Economic Potential of Plasma-Based CO2 Splitting in Power-to-Liquid Plants

Formate Dehydrogenase: From Nad(p)h Regeneration To the Target in Pathogens Biofilms, a Component Of Highly Efficient Hybrid Biocatalysts and Co2 Fixation From the Atmosphere

Two Steps Back, One Leap Forward: Synergistic Energy Conversion in Plasmonic and Plasma Catalysis

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CO₂reduction reactions: general discussion