Cobalt Nanoparticles Supported on Nitrogen‐Doped Carbon: An Effective Non‐Noble Metal Catalyst for the Upgrade of Biofuels

Jiang, Liang; Zhou, Peng; Liao, Chanjuan; Zhang, Zehui; Jin, Shiwei

doi:10.1002/cssc.201702078

Cited by 65 publications

(41 citation statements)

References 32 publications

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“…However, the carbonized MOFs consisting of metal NPs supported on a carbon structure show enhanced thermal and chemical stabilities, enabling their use under high temperature and pressure conditions. There are several reports of lignin HDO reactions with very high activation energies using carbonized MOFs 41,43,85 . Jiang et al .…”

Section: Production Of Porous Carbon‐supported Metal Catalysts Througmentioning

confidence: 99%

Modified Metal–Organic Frameworks as Efficient Catalysts for Lignocellulosic Biomass Conversion

Lee

Nam

2021

Bulletin Korean Chem Soc

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Biomass, a promising replacement for fossil fuels, can be used to produce eco‐friendly liquid fuels and chemicals. Various studies are investigating catalysts for lignocellulosic biomass conversion to valuable chemicals and fuels. Metal–organic frameworks (MOFs) are important catalysts because of their well‐ordered porous structures and large surface areas. Although MOFs can be applied directly, four modification strategies can be used to alter their catalytic properties and improve catalytic performance. In the first strategy, coordinatively unsaturated sites are created by changing the bonding state of the metal node. In the second approach, organic linkers with additional functional groups or active elements are used. In the third strategy, MOFs and other active elements are combined. In the final approach, MOFs are carbonized to produce carbon‐supported metal catalysts. We review the applications of modified MOFs for the catalytic conversion of biomass derivatives and discuss the factors that contribute to their improved catalytic performance.

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Section: Production Of Porous Carbon‐supported Metal Catalysts Througmentioning

confidence: 99%

Modified Metal–Organic Frameworks as Efficient Catalysts for Lignocellulosic Biomass Conversion

Lee

Nam

2021

Bulletin Korean Chem Soc

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“…During this same timeframe, another group, Zhang and co‐workers also reported a Co@N‐doped carbon catalyst derived from the pyrolysis of Co‐ZIF‐67. The resulting material catalyzes the deoxygenation of vanillin to produce 2‐methoxy‐4‐methylphenol and the one‐pot reductive amination of carbonyl compounds with nitro functionalities for the synthesis of secondary amines …”

Section: Mof‐derived Catalystsmentioning

confidence: 99%

Recent Advances of MOFs and MOF‐Derived Materials in Thermally Driven Organic Transformations

Yang

Bulut

et al. 2018

Chemistry A European J

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Owing to the almost boundless structural tunability, MOF and MOF-derived catalysts have recently exhibited structures of higher complexity, and hence, have demonstrated activity in a wide array of organic transformations. These reactions have a broad range of important applications ranging from pharmaceuticals to agriculture. Given the increasing number of publications in the area, this Minireview is focused on the most recent advancements in thermally driven organic transformations using both MOFs, nanoparticle@MOF (NP@MOF) composites, and several classes of MOF-derived materials. The most recent advancements made in materials design and the utility of these materials in a broad range of reactions are discussed.

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“…[23]. In particular, NC materials are widely used as catalyst supports, and perform well in the hydrodeoxygenation (HDO) of bio-phenolic compounds [24,25]. The introduction of N in the carbon structure modifies the electronic properties of the carbon matrix.…”

Section: Introductionmentioning

confidence: 99%

Catalytic Conversion of Palm Oil to Bio-Hydrogenated Diesel over Novel N-Doped Activated Carbon Supported Pt Nanoparticles

et al. 2019

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Bio-hydrogenated diesel (BHD), derived from vegetable oil via hydrotreating technology, is a promising alternative transportation fuel to replace nonsustainable petroleum diesel. In this work, a novel Pt-based catalyst supported on N-doped activated carbon prepared from polypyrrole as the nitrogen source (Pt/N-AC) was developed and applied in the palm oil deoxygenation process to produce BHD in a fixed bed reactor system. High conversion rates of triglycerides (conversion of TG > 90%) and high deoxygenation percentage (DeCOx% = 76% and HDO% = 7%) were obtained for the palm oil deoxygenation over Pt/N-AC catalyst at optimised reaction conditions: T = 300 °C, 30 bar of H2, and LHSV = 1.5 h−1. In addition to the excellent performance, the Pt/N-AC catalyst is highly stable in the deoxygenation reaction, as confirmed by the XRD and TEM analyses of the spent sample. The incorporation of N atoms in the carbon structure alters the electronic density of the catalyst, favouring the interaction with electrophilic groups such as carbonyls, and thus boosting the DeCOx route over the HDO pathway. Overall, this work showcases a promising route to produce added value bio-fuels from bio-compounds using advanced N-doped catalysts.

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Cobalt Nanoparticles Supported on Nitrogen‐Doped Carbon: An Effective Non‐Noble Metal Catalyst for the Upgrade of Biofuels

Cited by 65 publications

References 32 publications

Modified Metal–Organic Frameworks as Efficient Catalysts for Lignocellulosic Biomass Conversion

Modified Metal–Organic Frameworks as Efficient Catalysts for Lignocellulosic Biomass Conversion

Recent Advances of MOFs and MOF‐Derived Materials in Thermally Driven Organic Transformations

Catalytic Conversion of Palm Oil to Bio-Hydrogenated Diesel over Novel N-Doped Activated Carbon Supported Pt Nanoparticles

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