Collaborative Study for Certification of Trace Elements in Uranium Ore Concentrate CRMs UCLO-1, UCHI-1, and UPER-1

Abstract

Trace impurity patterns are important nuclear forensic signatures in uranium ore concentrates (UOCs) and Certified Reference Materials (CRMs) are used to validate the analysis methods employed by end users. Herein, we discuss the certification campaign for three new UOC CRMs from the National Research Council Canada: UCLO-1 (https://doi.org/10.4224/crm.2020.uclo-1), UCHI-1 (https://doi.org/10.4224/crm.2020.uchi-1), and UPER-1 (https://doi.org/10.4224/crm.2020.uper-1). This study involved 15 laboratories from 10 countries, using sector-field and (triple) quadrupole inductively-coupled plasma mass spectrometry to analyze 64 trace element impurities. We discuss the importance of the acids used for sample digestion, difficulties analyzing in a high uranium matrix, and data combination and uncertainty evaluation for this large dataset.

Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials

“…A certification campaign for three new uranium ore concentrate CRMs was discussed in a study by LeBlanc et al 198 Fifteen laboratories from 10 countries investigated sector field and ICP-MS/MS for the determination of 64 trace element impurities, with discussions around sample digestion techniques, high-U matrix analysis, as well as data handling and uncertainty evaluation.…”