Aquifer testing has shown that vertical hydraulic gradients exist in some wells in the 200 West Area. Vertical flow is upward in some places and downward in other places. The reason for the vertical flow is not known for certain. Nevertheless, vertical flow has important implications pertaining to (1) the representativeness of groundwater samples collected from monitoring wells and (2) the vertical distribution of contaminants in the aquifer.The major contaminants of concern in the groundwater below and locally adjacent to all single-shell tank waste management areas (WMAs) in 200 West Area are carbon tetrachloride, technetium-99, and nitrate. Chromium and tritium are contaminants present at WMAs T, TX-TY, and S-SX; iodine-129 is of concern at WMA TX-TY and fluoride is of concern at WMA T. The groundwater contaminants of concern below all single-shell tank WMAs in 200 East Area are nitrate, technetium-99, and tritium. Sulfate, uranium, cobalt-60, and cyanide are also of concern at WMA B-BX-BY, and cyanide is of concern at WMA C.Vertical concentration gradients are known to exist in the upper unconfined aquifer at several singleshell tank WMAs:• Around WMA T, maximum technetium-99 concentrations occur at the water table in some wells and 10 m below the water table in other wells east of the WMA.• Around WMA TX-TY, maximum concentrations of nitrate, technetium-99, and iodine-129 are within 1 m of the water table in the high concentration plume east of the WMA.• Around WMA S-SX, chromium, nitrate, and technetium-99 are present throughout the upper 23 m of the unconfined aquifer near the center of the plume south of the WMA. Technetium-99 and nitrate decrease rapidly with depth in the aquifer at a well near the northern edge of the plume.• Around WMA B-BX-BY, the concentration of tritium increases with increasing depth at one well. The concentrations of technetium-99 and nitrate are high in a zone at the base of the aquifer in another well at WMA B-BX-BY.
ivThe vertical concentration gradients are probably a function of several characteristics including distance to source area, salinity of waste fluids, and vertical hydraulic flow in the wells.Comparing the nitrate, technetium-99, and chromium concentrations in groundwater with concentrations in pore water representing leaked tank fluids suggests that tank waste has influenced groundwater at WMA T and WMA S-SX. Similar comparisons at WMA TX-TY and WMA B-BX-BY do not show similarities between groundwater, pore water and estimated tank fluid composition.v