Comment on “Synthesis and properties of high dielectric constant copolymer of a copper phthalocyanine oligomer grafted to amino-capped polyimide” by L. Chen, Y. Ding, T. Yang, C. Wan and H. Hou,<i>J. Mater. Chem. C</i>, 2017,<b>5</b>, 8371

Mezei, Gellert

doi:10.1039/c8tc04076a

J. Mater. Chem. C

2019

DOI: 10.1039/c8tc04076a

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Comment on “Synthesis and properties of high dielectric constant copolymer of a copper phthalocyanine oligomer grafted to amino-capped polyimide” by L. Chen, Y. Ding, T. Yang, C. Wan and H. Hou,J. Mater. Chem. C, 2017,5, 8371

Gellert Mezei

Abstract: Copper phthalocyanine prepared from pyromellitic dianhydride by Chen et al. and others is not fused-tetrameric, as claimed, but simple monomeric.

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Engineering the Dielectric Constants of Polymers: From Molecular to Mesoscopic Scales

Chen,

Pei,

Chai

et al. 2023

Advanced Materials

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Polymers are essential components of modern‐day materials and are widely used in various fields. The dielectric constant, a key physical parameter, plays a fundamental role in the light‐, electricity‐, and magnetism‐related applications of polymers, such as dielectric and electrical insulation, battery and photovoltaic fabrication, sensing and electrical contact, and signal transmission and communication. Over the past few decades, numerous efforts have been devoted to engineering the intrinsic dielectric constant of polymers, particularly by tailoring the induced and orientational polarization modes and ferroelectric domain engineering. Investigations into these methods have guided the rational design and on‐demand preparation of polymers with desired dielectric constants. This review article exhaustively summarizes the dielectric constant engineering of polymers from molecular to mesoscopic scales, with emphasis on application‐driven design and on‐demand polymer synthesis rooted in polymer chemistry principles. Additionally, it explores the key polymer applications that can benefit from dielectric constant regulation and outlines the future prospects of this field.

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Engineering the Dielectric Constants of Polymers: From Molecular to Mesoscopic Scales

Chen,

Pei,

Chai

et al. 2023

Advanced Materials

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Intrinsic polymer dielectrics for high energy density and low loss electric energy storage

Wei

Zhu

2020

Progress in Polymer Science

214

126

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Comment on “Synthesis and properties of high dielectric constant copolymer of a copper phthalocyanine oligomer grafted to amino-capped polyimide” by L. Chen, Y. Ding, T. Yang, C. Wan and H. Hou,J. Mater. Chem. C, 2017,5, 8371

Abstract: Copper phthalocyanine prepared from pyromellitic dianhydride by Chen et al. and others is not fused-tetrameric, as claimed, but simple monomeric.

Cited by 2 publications

References 78 publications

Engineering the Dielectric Constants of Polymers: From Molecular to Mesoscopic Scales

Engineering the Dielectric Constants of Polymers: From Molecular to Mesoscopic Scales

Intrinsic polymer dielectrics for high energy density and low loss electric energy storage

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