Wet-Chemical Synthesis of Doped Colloidal Nanomaterials: Particles and Fibers of LaPO 4 :Eu, LaPO 4 :Ce, and LaPO 4 :Ce,Tb.Lanthanoid-doped LaPO 4 nanomaterials are prepared in the high-temperature monazite phase in two morphologies (particles and fibers) via a low-temperature synthesis. The symmetry of the main dopant site is determined from the Eu 3+ emission to be the same as in bulk LaPO 4 .