2022
DOI: 10.1039/d1fd00059d
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Comparative analysis of lanthanide excited state quenching by electronic energy and electron transfer processes

Abstract: The relative sensitivity of structurally related Eu(III) complexes to quenching by electron and energy transfer processes has been compared. In two sets of 9-coordinate complexes based on 1,4,7-triazacyclonane, the Eu...

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Cited by 5 publications
(2 citation statements)
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“…Here, we focus on the need to differentiate between observed emission intensity and actual transition probability. The latter is determined exclusively by electron structure, while the former is affected by several parameters . Using the emission intensity as a single parameter in, for example, a binding study thus potentially leads to significant errors.…”
mentioning
confidence: 99%
“…Here, we focus on the need to differentiate between observed emission intensity and actual transition probability. The latter is determined exclusively by electron structure, while the former is affected by several parameters . Using the emission intensity as a single parameter in, for example, a binding study thus potentially leads to significant errors.…”
mentioning
confidence: 99%
“…[46] In this context, numerous published literatures have reported the excited-state dynamics of lanthanides. [47][48][49] Sensitizer ligands offer effective energy absorption capabilities for luminophores, and their sensitization pathway comprises both forward and backward energytransfer processes in the excited state. Various energy transfer pathways are better presented diagrammatically in Figure 11d.…”
Section: Lanthanides Complexesmentioning
confidence: 99%