Comparative elemental characterization of atmospheric fine and coarse PM samples by PIXE and ICP-MS/MS: results from a one-year measurement campaign in a coal-powered thermal power plant city

Dawood, Abdallah M. A.; Lucarelli, F.; Arı, Akif; Can, Emre; Arı, Pelin Ertürk; Döğeroğlu, Tuncay; Gaga, Eftade O.

doi:10.1039/d2ja00251e

Cited by 2 publications

(1 citation statement)

References 78 publications

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“…This exercise is timely because as air becomes cleaner, lower measurement LODs are required so the use of ICP-MS could supersede that of XRFS. In a similar study, a comparison of ICP-MS/MS and PIXE measurements of Al, As, Br, Ca, Cr, Cu, Fe, Mg, Mn, Mo, Na, Ni, Pb, Rb, S, Se, Sr, Ti, V, Zn and Zr in PM 2.5 and PM 2.5-10 lter samples demonstrated 28 that paired-data ratios were mostly ca. 1 except for those of Br, Mg, Na and Zr.…”

Section: Reference Materials and Instrumental Intercomparisonsmentioning

confidence: 75%

Atomic spectrometry update – a review of advances in environmental analysis

Bacon,

Butler,

Cairns

et al. 2024

J. Anal. At. Spectrom.

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Section: Reference Materials and Instrumental Intercomparisonsmentioning

confidence: 75%

Atomic spectrometry update – a review of advances in environmental analysis

Bacon,

Butler,

Cairns

et al. 2024

J. Anal. At. Spectrom.

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Impact of dry deposition flux and dust intrusion phenomena on elemental concentrations of air particulate matter

Dawood

Akortia²,

Alsufyani³

et al. 2023

Front. Environ. Sci.

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Depositions of trace elements of air particulates in the atmosphere have gained much attention in recent times due to their environmental, climatic and health impacts. In the current study, trace elements of size-segregated rural and urban particulate matter (PM2.5 and PM2.5−10) were characterized using particle-induced X-ray emission method. Effects of dry deposition flux and Saharan dust intrusion on the elemental concentrations were determined. The mean elemental concentration in the rural fine PM ranged between 0.0002 ± 0.0002 μg m−3 (for Se) and 0.6658 ± 0.5816 μg m−3 (for S) whereas in the urban fine PM the concentration ranged between 0.0007 ± 0.0008 μg m−3 (for As) and 0.5869 ± 0.3429 μg m−3 (for Ca). In the coarse PM fraction, concentration ranged between 0.0001 ± 0.0001 μg m−3 (for Se) and 0.5886 ± 0.5343 μg m−3 (for Ca) at the rural site; and between 0.0002 ± 0.0002 μg m−3 (for Se) and 1.9201 ± 1.911 μg m−3 (for Ca) at the urban site. Mainly crustal elements (Al, Ca, Fe) and ‘pollution’ source element (S) recorded high and significant dry deposition fluxes across the two sites in both PM modes. Deposition flux was relatively higher in the coarse than in the fine PM mode. The average dry deposition flux estimated for fine and coarse PM at the rural and urban sites were 33.68 ± 57.19 μg m−2 day−1 and 47.71 ± 92.19 μg m−2 day−1; 36.66 ± 61.95 μg m−2 day−1 and 107.02 ± 237.71 μg m−2 day−1, respectively. Mainly crustal (Al, Ca, Fe) and “pollution” (S) element recorded high and significant dry deposition fluxes across the two sites and in the two PM modes. The impacts of dust on climate, air quality, and the environment in general have increased the need to better understand the dust flow system. In the current study, dust intruding the study area from the Sahara was analyzed using the NMMB/BSC dust model. The model’s output indicated that, the highest daily surface dust concentration was observed in the central and south-west of Turkey which corresponded with the peak period of Saharan dust transport to the Eastern Mediterranean in the month of March.

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Comparative elemental characterization of atmospheric fine and coarse PM samples by PIXE and ICP-MS/MS: results from a one-year measurement campaign in a coal-powered thermal power plant city

Abstract: Daily fine (PM2.5) and coarse (PM2.5-10) particulate matter samples were collected from rural and urban monitoring stations located in an industrial region of mid-western Turkey, Kütahya city during one year...

Cited by 2 publications

References 78 publications

Atomic spectrometry update – a review of advances in environmental analysis

Atomic spectrometry update – a review of advances in environmental analysis

Impact of dry deposition flux and dust intrusion phenomena on elemental concentrations of air particulate matter

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