Comparative Study of Molecular Interactions in Binary Liquid Mixtures of 4 –Methyl-2-pentanoneWith Butan-2-One, Furfuraldehyde, Cyclohexanone At 308 K

Ubagaramary, D.; Kesavaswamy,; Enoch, Muthu Vijayan

doi:10.13005/ojc/320136

Cited by 4 publications

(1 citation statement)

References 4 publications

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“…Viscosities were determined by Oswald viscometer 10 mL capability with an accurateness of ± 0.001 cP [18]. From the measured values of density and flow time 't', viscosity 'η' was calculated.…”

Section: Viscosity (η)mentioning

confidence: 99%

Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies

Uthirapathi¹,

KİSHNAMOORTHY²,

AMBROSE³

2022

International Journal of Thermodynamics

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A study on thermodynamic properties of the liquid mixture is used in the industrial process, which often extends to solution chemistry. Density(ρ), Viscosity(η), and Ultrasonic velocity(U) were determined for binary liquid mixtures of furfural with chlorobenzene, nitromethane, diethyl malonate and 1- butanol at temperature of 308.15K and 318.15K at atmospheric pressure over the whole range of mole fractions. The calculated thermodynamic properties and some excess parameters such as Excess Volume(VE), Deviation in Isentropic Compressibility(∆KS), Deviation in Viscosity(∆η), Deviation in Intermolecular Free Length(∆LF), Deviation in Intermolecular Free Volume(∆VF), Deviation in Internal Pressure(∆π) and Deviation in Acoustic Impedance(∆Z) were calculated and applied to the Redlich-Kister type polynomial equation to determine the appropriate coefficients. The effects of composition and temperature on thermodynamic parameters have been studied in terms of molecule interaction in these liquid mixtures. Further, IR spectra of these liquid mixtures were recorded and the data were utilized to examine the mixing behavior of the components.

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Section: Viscosity (η)mentioning

confidence: 99%

Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies

Uthirapathi¹,

KİSHNAMOORTHY²,

AMBROSE³

2022

International Journal of Thermodynamics

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Study of solute–solvent interaction in the solutions of PVA with PEG at 338 K by ultrasonic technique

Verma

Pandey

Mohan

et al. 2022

Materials Today: Proceedings

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Thermodynamic Properties of Binary Liquid Mixtures of Furfural with Toluene and Nitro Benzene at Varying Temperatures

2022

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Binary liquid mixtures of furfural with toluene and nitrobenzene were examined for ultrasonic velocity, viscosity and density at a temperature of 308.15 and 318.15 K in various mole fractions. The calculated thermodynamic properties from density, viscosity, ultrasonic velocity and some excess parameters like Excess Volume(VE), Deviation in Isentropic Compressibility(∆KS), Deviation in Viscosity(∆η), Deviation in Intermolecular Free Length(∆LF), Deviation in Intermolecular Free Volume(∆VF) and Deviation in Acoustic Impedance(∆Z) were determined and found the proper coefficients for a polynomial equation of the Redlich - Kister type, from which the theoretical values were calculated. The interaction ability of the binary liquid mixtures was investigated, as well as the deviations of the binary liquid mixtures from their ideal behavior were studied based on the experiment and theoretical values.

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Comparative Study of Molecular Interactions in Binary Liquid Mixtures of 4 –Methyl-2-pentanoneWith Butan-2-One, Furfuraldehyde, Cyclohexanone At 308 K

Cited by 4 publications

References 4 publications

Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies

Thermodynamic Properties of Binary Liquid Mixtures Containing Furfural with Chlorobenzene, Nitromethane, Diethylmalonate and 1-Butanol at 308.15K and 318.15K Supported by FTIR Spectral Studies

Study of solute–solvent interaction in the solutions of PVA with PEG at 338 K by ultrasonic technique

Thermodynamic Properties of Binary Liquid Mixtures of Furfural with Toluene and Nitro Benzene at Varying Temperatures

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