Comparison of dried matrix spots and fabric phase sorptive extraction methods for quantification of highly potent analgesic activity agent (2R,4aR,7R,8aR)-4,7-dimethyl-2-(thiophen-2-yl)octahydro-2H-chromen-4-ol in rat whole blood and plasma using LC–MS/MS

Lastovka, Anastasiya V.; Rogachev, Artem D.; Ильина, И. В.; Kabir, Abuzar; Волчо, К. П.; Fadeeva, V. P.; Pokrovsky, Andrey G.; Furton, Kenneth G.; Salakhutdinov, N. F.

doi:10.1016/j.jchromb.2019.121813

Cited by 3 publications

(1 citation statement)

References 32 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Lastovka et al in 2019 [ 47 ] developed a method for the quantification of highly potent analgesic agent (2 R ,4a R ,7 R ,8a R )-4,7-dimethyl-2-(thiophen-2-yl)octahydro-2 H -chromen-4-ol in rat whole blood and plasma using dried matrix spots (DMS) and fabric phase sorptive extraction (FPSE) techniques in combination with LC–MS/MS. The linearity was obtained in the range of 20–5000 ng/mL and 50–5000 ng/mL for plasma-FPSE and blood-FPSE experiments, respectively.…”

Section: Applicationsmentioning

confidence: 99%

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Kabir

Samanidou

2021

Molecules

Self Cite

View full text Add to dashboard Cite

Fabric phase sorptive extraction (FPSE) is an evolutionary sample preparation approach which was introduced in 2014, meeting all green analytical chemistry (GAC) requirements by implementing a natural or synthetic permeable and flexible fabric substrate to host a chemically coated sol–gel organic–inorganic hybrid sorbent in the form of an ultra-thin coating. This construction results in a versatile, fast, and sensitive micro-extraction device. The user-friendly FPSE membrane allows direct extraction of analytes with no sample modification, thus eliminating/minimizing the sample pre-treatment steps, which are not only time consuming, but are also considered the primary source of major analyte loss. Sol–gel sorbent-coated FPSE membranes possess high chemical, solvent, and thermal stability due to the strong covalent bonding between the fabric substrate and the sol–gel sorbent coating. Subsequent to the extraction on FPSE membrane, a wide range of organic solvents can be used in a small volume to exhaustively back-extract the analytes after FPSE process, leading to a high preconcentration factor. In most cases, no solvent evaporation and sample reconstitution are necessary. In addition to the extensive simplification of the sample preparation workflow, FPSE has also innovatively combined the extraction principle of two major, yet competing sample preparation techniques: solid phase extraction (SPE) with its characteristic exhaustive extraction, and solid phase microextraction (SPME) with its characteristic equilibrium driven extraction mechanism. Furthermore, FPSE has offered the most comprehensive cache of sorbent chemistry by successfully combining almost all of the sorbents traditionally used exclusively in either SPE or in SPME. FPSE is the first sample preparation technique to exploit the substrate surface chemistry that complements the overall selectivity and the extraction efficiency of the device. As such, FPSE indeed represents a paradigm shift approach in analytical/bioanalytical sample preparation. Furthermore, an FPSE membrane can be used as an SPME fiber or as an SPE disk for sample preparation, owing to its special geometric advantage. So far, FPSE has overwhelmingly attracted the interest of the separation scientist community, and many analytical scientists have been developing new methodologies by implementing this cutting-edge technique for the extraction and determination of many analytes at their trace and ultra-trace level concentrations in environmental samples as well as in food, pharmaceutical, and biological samples. FPSE offers a total sample preparation solution by providing neutral, cation exchanger, anion exchanger, mixed mode cation exchanger, mixed mode anion exchanger, zwitterionic, and mixed mode zwitterionic sorbents to deal with any analyte regardless of its polarity, ionic state, or the sample matrix where it resides. Herein we present the theoretical background, synthesis, mechanisms of extraction and desorption, the types of sorbents, and the main applications of FPSE so far according to different sample categories, and to briefly show the progress, advantages, and the main principles of the proposed technique.

show abstract

Section: Applicationsmentioning

confidence: 99%

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Kabir

Samanidou

2021

Molecules

Self Cite

View full text Add to dashboard Cite

show abstract

Determination of elemental impurities Cd, Pb, As, Hg, Co, V, Ni, Pd, Ru, Ag, Pt, Mo, Al, and Fe in highly potent analgesic activity agent by microwave-induced plasma optical emission spectrometry (MIP OES)

et al. 2022

View full text Add to dashboard Cite

Fabric Phase Sorptive Extraction: Unifying Solid Phase Microextraction and Solid Phase Extraction by Design

Kabir

Olayanju

Furton

2023

Evolution of Solid Phase Microextraction Technology

View full text Add to dashboard Cite

A fabric phase sorptive extraction (FPSE) device has gained considerable popularity in recent years as a novel sample preparation device for the rapid monitoring of a myriad of target analytes in biological, environmental, forensic, food and pharmaceutical samples. This extraction device is fabricated via a sol–gel sorbent coating process which enables strong chemical bonding between the flexible fabric substrate and the sorbent immobilized on the substrate's surface. The inherent material properties of the sol–gel sorbent and the chemically bonded sorbent on the fabric substrate endow FPSE membranes with high thermal, chemical and solvent stability. The number of available sorbents in FPSE outnumbers that of any other sample preparation techniques and offers a broad range of sorbents with distinct chemistries which could establish specific interactions (e.g., hydrogen bonding, dipole–dipole interactions, London dispersion force, π–π interactions and others) with the target analytes. Fabric phase sorptive extraction has integrated the extraction mechanisms of solid phase extraction (exhaustive extraction) and solid phase microextraction (equilibrium extraction) by design. When an FPSE membrane is introduced into the sample matrix, it mimics an SPME fiber. During the extraction, the aqueous sample matrix continuously permeates through the pores of the FPSE membrane that mimics a solid phase extraction disk. The combination of the extraction mechanisms of two major, yet competing sample preparation technologies, sponge-like porous architecture of sol–gel sorbents, improved thermodynamic properties due to the combination of organic and inorganic components and faster extraction kinetics have positioned FPSE as an ideal sample preparation technology in the field of analytical and bioanalytical chemistry.

show abstract

Comparison of dried matrix spots and fabric phase sorptive extraction methods for quantification of highly potent analgesic activity agent (2R,4aR,7R,8aR)-4,7-dimethyl-2-(thiophen-2-yl)octahydro-2H-chromen-4-ol in rat whole blood and plasma using LC–MS/MS

Cited by 3 publications

References 32 publications

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Fabric Phase Sorptive Extraction: A Paradigm Shift Approach in Analytical and Bioanalytical Sample Preparation

Determination of elemental impurities Cd, Pb, As, Hg, Co, V, Ni, Pd, Ru, Ag, Pt, Mo, Al, and Fe in highly potent analgesic activity agent by microwave-induced plasma optical emission spectrometry (MIP OES)

Fabric Phase Sorptive Extraction: Unifying Solid Phase Microextraction and Solid Phase Extraction by Design

Contact Info

Product

Resources

About